What is the ionization potential for an electron going from n = 2n=2 to n = 3n=3 in "eV"eV for hydrogen atom?

1 Answer
Jun 22, 2017

About "1.89 eV"1.89 eV is released for the absorption, or absorbed for the emission process between n = 3n=3 and n = 2n=2. That means it takes about 1.891.89 "eV"eV of work to accelerate one electron through a one potential difference of one volt.

To be accurate, I don't think that's an ionization potential... that's really the energy used to excite the atom (ionization potential is for removing electron(s) altogether).


I think you're asking about the change in energy going from n = 3n=3 to n = 2n=2 in the hydrogen atom? That can be found from the Rydberg equation:

DeltaE = -"13.6 eV" (1/n_f^2 - 1/n_i^2)

where:

  • "13.6 eV" is the Rydberg constant in electron volts (or the negative of the hydrogen atom ground state energy).
  • n_i is the initial state's principal quantum number n.
  • n_f is the final state's principal quantum number n.

So, if you wanted the final state to be E_3, then:

DeltaE = color(blue)(E_3 - E_2) = -"13.6 eV" (1/3^2 - 1/2^2)

= color(blue)("1.89 eV")