What is the geometry of the Cl-S-S-Cl molecule?

1 Answer
anor277
Jun 12, 2017

"Disulfur dichloride" is typically bent........and an analogue of "hydrogen peroxide".

Explanation:

"Disulfur dichloride" is typically bent........and the /_Cl-S-S-Cl torsional angle is approx. 90^@. This gives rise to a polar molecule. It is a distillable liquid that smells absolutely foul.

With water, this material undergoes disproportionation:

2Cl-S-S-Cl + 2H_2O rarrSO_2(g) +4HCl(aq) +3/8S_8(s)

Can you assign the sulfur oxidation states?

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