Question #27e1c

1 Answer
Jul 19, 2017

00

Explanation:

Your goal here is to figure out if "9.9 eV"9.9 eV of energy are enough to excite a hydrogen atom in its ground state and if so, the highest energy level that the electron can reach.

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The easiest way you have of figuring out if "9.9 eV"9.9 eV is enough energy to bump the electron from the first energy level is to subtract the energy of the ground level, for which n=1n=1, and the energy of the first excited state, for which n=2n=2.

You will end up with--you can ignore the minus signs for this purpose

"13.6 eV " - " 3.40 eV" = "10.2 eV"13.6 eV 3.40 eV=10.2 eV

This tells you that in order for an electron to move from n=1n=1 to n=2n=2 in a hydrogen atom, it must absorb "10.2 eV"10.2 eV of energy.

Since you only have "9.9 eV"9.9 eV available, you can say that the electron won't absorb the energy needed for this transition to take place, which implies that the number of spectral lines emitted will be equal to 00.

Alternatively, you can use the fact that the quantized energy levels that the electron can occupy in a hydrogen atom are described by the following equation

E_n = -"13.6 eV"/n^2En=13.6 eVn2

Here nn represents the principal quantum number that describes a given energy level.

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In your case, you will have

E_n = -"13.6 eV" + "9.9 eV" = -"3.7 eV"En=13.6 eV+9.9 eV=3.7 eV

This means that nn will be

n^2 = (color(red)(cancel(color(black)(-)))13.6 color(red)(cancel(color(black)("eV"))))/(color(red)(cancel(color(black)(-)))3.7color(red)(cancel(color(black)("eV")))) implies n= sqrt(13.6/3.7) ~~ 1.9

Since you have 1 < n < 2, you can conclude that the electron did not absorb enough energy to get to the second energy level -> no spectral lines will be emitted.