Question #e3210

1 Answer
Apr 12, 2017

By separating the individual redox reactions, and assigning oxidation numbers.

Explanation:

Silver metal is oxidized to silver ion:

#stackrel(0)Ag rarr stackrel(+I)Ag^(+) +e^-# #(i)#

Nitrate ion is reduced to nitrogen monoxide:

#stackrel(+V)NO_3^(-) +4H^(+) + 3e^(-) rarr stackrel(+II)NO +2H_2O# #(ii)#

We add these half equations together to eliminate the electrons:

#3xx(i) + (ii):#

#3Ag + NO_3^(-) +4H^(+) rarr 3Ag^(+) + NO +2H_2O#

Is this balanced with respect to mass and charge? If it is not, it cannot be accepted as a representation of chemical (i.e. physical) reality.

While it might seem a little abstract to include electrons as fundamental reactants and products in these redox transfer processes, their use, as a convenient little fiction, allows us to address these types of problems.

For another example of this type of redox process, see [here.](https://socratic.org/questions/how-can-i-adjust-this-redox-equation-h2o2-crcl3-koh-k2cro4-kcl-h2o-thanks) And also see [here and links for other examples.](https://socratic.org/questions/by-half-reaction-method-1)