Balanced equation
#"B"_2"H"_6("g") + "3O"_2("g")"##rarr##"B"_2"O"_3("s") + "3H"_2"O(g)"#
We first need to determine mol #"B"_2"H"_6"# by dividing its given mass by its molar mass #("25.652 g/mol")#. Divide by multiplying by the reciprocal of its molar mass (mol/g).
#17.2color(red)cancel(color(black)("g B"_2"H"_6))xx(1"mol B"_2"H"_6)/(25.652color(red)cancel(color(black)("g B"_2"H"_6)))="0.671 mol B"_2"H"_6"#
To determine mol #"H"_2"O"# produced, multiply mol #"B"_2"H"_6"# by the mol ratio between #"H"_2"O"# and #"B"_2"H"_6"# from the balanced equation, with #"H"_2"O"# in the numerator.
#0.671color(red)cancel(color(black)("mol B"_2"H"_6))xx(3"mol H"_2"O")/(1color(red)cancel(color(black)("mol B"_2"H"_6)))="2.01 mol H"_2"O"#
The complete combustion of #"17.2 g B"_2"H"_6"# produces #"2.01 mol H"_2"O"#.