Question #1ae6a

1 Answer
Oct 26, 2017

The reason for this is that aqueous KOH being alkaline in
nature gives OH
ions. These OH ions then act as strong
nucleophile and attack on electrophilic carbon of alkyl halide
molecule. Thus the leaving group leaves and OH substitute the halogen atom of alkyl halide molecule, forming alcohol as a product. Consequently, aqueous KOH gives substitution reactions.

On the other hand, alcoholic KOH(mostly having ethanol) produces C2H5O ions which are stronger base than OH ions. So these abstract the β- hydrogen of alkyl halide molecule, forming an alkene. That's the reason behind the statement; Alcoholic KOH give elimination reactions.

Hope it helps...