For a given strong acid HA, is the concentration of A^- likely to be high or low at equilibrium?

1 Answer
Feb 23, 2017

This is a good question, and it is clear that HY is the STRONGER ACID..........

Explanation:

The strength of an acid, HA, in an aqueous medium, is dictated SOLELY by the extent the given equilibrium lies to the RIGHT (as we face the page):

HA(aq) + H_2O(l) rightleftharpoons H_3O^(+) + A^-

And thus for strong acids, the equilibrium lies to the right, and more of the solvent molecules are conceived to be protonated to give the H_3O^+("hydronium ion").

(a) In the diagram, for HY, there is a greater number (i.e. concentration) of such hydronium ions, and thus the equilibrium lies farther to the right. On this basis, HY is a stronger acid than HX in that there are more hydronium ions..........

(b) And if HY is the stronger acid, it is clear that Y^- is the WEAKER conjugate base (why? again because Y^- competes poorly for the proton). So X^- is the STRONGER base.

(c) Given equal concentrations of HX and Y^-, since X^- is the stronger base, the GIVEN equilibrium,

HX(aq) + Y^(-) rightleftharpoons X^(-) + HY(aq)

will lie to the LEFT as written.......

This question is certainly non-trivial, and would tax most 2nd year/3rd year inorganic chemistry students......anyway, please criticize my reasoning if there is an issue.