What is the difference between the Rydberg constants RH=109678.77 cm1 and R=109737.32 cm1?

1 Answer
Jan 5, 2017

It just depends on what kinds of atoms you use it for.

These Rydberg constants are (Inorganic Chemistry, Miessler et al.):

R=1.097373156853955×107 m1

=109737.3156853955 cm1

RH=1.096787717430710×107 m1

=109678.7717430710 cm1

where subscript digits indicate digits of high uncertainty.

R, the constant for the limit of "infinite" nuclear mass, is used for heavy atoms, which have a heavy nucleus, considered to be "infinitely" heavier than the mass of each electron.

RH, the constant for the proton nuclear mass, is used for hydrogen atom only, because its nucleus is only one proton, which is about 1836.15 times as heavy as an electron, but not "infinitely" heavier.