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Answer 1 · 2016-12-20T11:19:49

Iron is more electropositive than Silver as evident from their positions in the electrochemical series.Less electropoitve Silver ions $(A g^{+})$ $(Ag^+)$ get reduced by the Iron $F e$ $Fe$ atom and as a result metallic silver is deposited on Iron electrode when dipped in silver ion solution. But Ag electrode does not interact with $F e^{+3}$ $Fe^"+3"$ ions in solution.

$2 A g^{+} + F e \to F e^{+2} + 2 A g$ $2Ag^+ +Fe->Fe^"+2"+2Ag$

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