What would occur in the reaction between "potassium permanganate", KMnO_4 and "sodium sulfite", Na_2SO_3?

1 Answer
Oct 6, 2016

A redox reaction occurs. Sulfite should be oxidized to sulfate. Permanganate ion should be reduced to Mn^(2+).

Explanation:

"Reduction half equation: "Mn(VII+) rarr Mn(II+)

MnO_4^(-) +8H^(+) + 5e^(-) rarr Mn^(2+) + 4H_2O (i)

"Oxidation half equation: "S(IV+) rarr S(VI+)

SO_3^(2-) +H_2O rarr SO_4^(2-) + 2H^(+) + 2e^(-) (ii)

Both equations are (I think) balanced with respect to mass and charge, as they must be if they reflect reality. The overall redox reaction excludes the electrons; so we take 2xx(i)+5xx(ii):

2MnO_4^(-) +5SO_3^(2-)+6H^(+)rarr 2Mn^(2+) + 5SO_4^(2-)+3H_2O

Which is (I think) balanced with respect to mass and charge.

So what would you observe in this reaction? MnO_4^- is strongly coloured, and gives a beautiful deep purple solution. On the other hand, Mn^(2+) is almost colourless (very concentrated solutions are a pale rose). And thus this redox reaction is self-indicating, and proposes that 2 "equiv" permanganate reacts with 5 "equiv" of sulfite.

How did I know the oxidation/reduction products? Experience and practice, and actually doing the titrations and observing and explaining the colour change.