Question #b39e8
1 Answer
By Clausius - Clapeyron equation weknow
color(red)(ln(P_1/P_2) = (DeltaH_"vap")/R xx (1/T_2 - 1/T_1)
Where
P_1 is the vapor pressure of the liquid atT_1K
P_2 is the vapor pressure of the liquid atT_2K
R is the universal gas constant, equal to"8.314J mol"^(-1)"K"^(-1)
DeltaH_"vap"= "enthalpy of vaporization of the liquid"
Given
Inserting these in above equation
color(blue)(ln(P_1/P_2) = (DeltaH_"vap")/R xx (1/T_2 - 1/T_1)
=>color(blue)(ln(8.54/P_2) = (41.8xx10^3)/8.314xx (1/393 - 1/278)
=>color(blue)(ln(8.54)-lnP_2 = (41.8xx10^3)/8.314xx (1/393 - 1/278))
=>color(blue)(lnP_2 =ln(8.54)- (41.8xx10^3)/8.314xx (1/393 - 1/278))
=>color(blue)(lnP_2=7.437)
=>color(blue)(P_2=e^7.437~~1698mm)