Question #62993

1 Answer
Feb 21, 2016

Yes, we can.

Explanation:

You're dealing with the hydrolisis of boron trichloride, "BCl"_3.

This reaction will produce boric acid, which you'll see written both as "H"_3"BO"_3 and as "B"("OH")_3, and hydrochloric acid, "HCl".

The balanced chemical equation would indeed look like this

"BCl"_text(3(aq]) + 3"H"_2"O"_text((l]) -> "B"("OH")_text(3(aq]) + 3"HCl"_text((aq])

I'll try to explain what's going on here without going into too much detail. Mind you, this is a simplified version of what actually goes on, but it will give you an idea of how things work here.

The boron atom in boron trichloride, which is "sp"^2 hybridized, has an empty 2p-orbital.

![http://www.tutorvista.com/content/chemistry/chemistry-iv/p-block-elements/http://reactivity-elements.php](https://useruploads.socratic.org/mX6pZJk4SCe06DaT1Fvr_boron-trihalides-structure.jpeg)

This means that it can act as a Lewis acid, i.e .accept a pair of electrons from the oxygen atom of a water molecule.

This will lead to the formation of an adduct, which is simply the result of the addition of two molecules.

Once this adduct, which can be represented as ["H"_2"O"-"BCl"_3]^(-), is formed, a hydrogen atom located on the water molecule will jump off, leaving an "OH"- group attached to the boron trichloride.

This will trigger the replacement of the "B"-"Cl" bonds with stronger "B"-"O" bonds, resulting in the formation of boric acid, "B"("OH")_3.

![npic.orst.edu)

As an interest follow-up, boric acid acts as an acid not because it donates protons, "H"^(+), but because it pulls another -"OH" group from water to form the tetrahydroxyborate anion, ["B"("OH")_4]^(-)

"B"("OH")_text(3(aq]) + "H"_2"O"_text((l]) rightleftharpoons ["B"("OH")_text(4(aq])]^(-) + "H"_text((aq])^(+)