For the reaction 2 A + B ---> Products, the following initial rate data was collected? [A] [B] Initial Rate 0.01 M 0.01 M 0.002 M/sec 0.03 M 0.02 M 0.0024 M/sec 0.03 M 0.01 M 0.006 M/sec

[A] [B] Initial Rate
0.01 M 0.01 M 0.002 M/sec
0.03 M 0.02 M 0.024 M/sec
0.03 M 0.01 M 0.006 M/sec

(a) What is the order of reaction for each reactant? Overall?
(b) What are the units of the rate constant?
(c) What is the value of the rate constant?

1 Answer
Feb 25, 2018

a. Overall third order, A to the first, B to the second
b. #mol^-2dm^6s^-1#
c. #2000#

Explanation:

When A is tripled in trial 3 from trial 1, and B is kept constant the rate also triples, so A is to the first order.

When A is kept constant from trial 3 to trial 2 but B is doubled, the rate quadruples, therefore B is to the second order.

Determining K
#K=(0.002M/sec)/((0.01M)*(0.01M)^2)#