Why is the normal boiling point of a liquid the point at which the vapor pressure is equal to atmospheric pressure, #"760 torr"#?

1 Answer

The boiling point of water is established relative to standard atmospheric pressure of 101.325 kilopascals which is the pressure experienced by a square meter of atmosphere pressing down on the surface of the earth.

Explanation:

Boiling point is established relative to the standard atmosphere. The standard atmosphere is based upon the weight of a column of earth's atmosphere at the surface (average sea level) with specific dimensions.

In general, pressure is defined as force per unit area.

#P = F/A#

That is, given a column of earth's atmosphere having the dimensions of one square meter at earth's surface and an altitude up to the top of the mesosphere would exert an average force/area of #101.325# kilonewtons per square meter (#"kN/m"^2#), or

#"101.325 kPa"# #=# #"760 torr"#.

At this atmospheric pressure, the boiling point of water is #100^@ "C"# and accepted as the normal boiling point of water, i.e. the boiling point at this normal pressure.