Question #51815

1 Answer
Oct 7, 2017

The process in which solid crystals are deposited when the concentration of a solute in a solution increases past the point of saturation.

Explanation:

Methods of Crystallisation

  • Occurs when the unsaturated solution becomes saturated and crystals form.

  • Cooling a solution may reduce the solubility of a dissolved solute to the point where not all of the substance present is soluble.

  • Evaporation of solvent from a solution

Variables Affecting Crystal Growth

  • Rate of Cooling of a Solution or Molten Compound
    o Slow cooling = large crystals
    o Rapid cooling = smaller crystals

  • Rate of Evaporation of solvent
    o Faster evaporation = smaller crystals

  • Nucleation
    o Nucleus = single seed crystal of the compound itself
    o A small solid impurity can also act as a nucleus.
    ♣ E.g. dust/scratch on container

  • Nature of the Compound
    o Different compounds = different shaped crystals

Source: Heinemann Chemistry 1 (5th Edition)