What is the oxidation half reaction for Mg(s)+ZnCl2(ag)MgCl2(ag)+Zn(s)?

2 Answers
Jan 11, 2017

The oxidation half-reaction is

Mg(s)Mg2++2e

Explanation:

If you write what is known as the net ionic equation, it is a simpler matter to identify the oxidation (and the reduction form that matter).

First, write the two salts in aqueous ion form:

Mg(s)+Zn2+(aq)+2Cl1(aq)Zn(s)+Mg2+(aq)+2Cl1(aq)

Since no change occurs in the chloride ion, these are "spectators" and can be omitted:

Mg(s)+Zn2+(aq)Zn(s)+Mg2+(aq)

Now, we have a more clear description of what has taken place.

Zn2+ has been reduced to Zn(s)

Mg(s) has been oxidized to Mg2+

Jan 12, 2017

Anode: Mg → Mg2+ + 2e- 2.38V

Explanation:

From the equation we see that Mg metal (oxidation state 0) changes to the ion Mg2+. It is thus “oxidized” and is the reducing agent. It is thus the anode of the cell.

Zn is changed from it’s ionic state, Zn2+ to its metallic state of 0. It is thus “reduced” and is the oxidizing agent. It is thus the cathode of the cell.

By convention, all half-cell emf's are compared to the emf of the standard hydrogen electrode. The emf of a half-cell, with respect to the standard hydrogen electrode, is called the reduction potential.
In an electrochemical cell, the general equation is:

E=Eo(red) (cathode) - Eo(red) (anode)

The emf for the Mg-Zn cell described would be:

E=Eo(red)(Zn) - Eo(red)(Mg) = -0.76 - (-2.38) = 1.62V if the solutions are 1.0 M.

The two “standard cell” cathode (reduction) half reactions are:
Mg2+ + 2e- → Mg - 2.38V
Zn2+ + 2e- → Zn - 0.76V
http://hyperphysics.phy-astr.gsu.edu/hbase/Tables/electpot.html

Put in the general equation for the actual cell, the full reaction is:
Mg + Zn2+Mg2+ + Zn
-0.76 - (-2.38) = 1.62V